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Beilstein J. Org. Chem. 2015, 11, 678–686, doi:10.3762/bjoc.11.77
Graphical Abstract
Figure 1: A) Schematic drawing of a bifunctional anchor molecule and its immobilization on a nanoparticle (NP...
Scheme 1: Synthesis of tripodal catecholates for surface immobilization. PEG-triscatecholate 3 was synthesize...
Scheme 2: Synthesis of tripodal catecholate platforms 11 and 13 for surface functionalization.
Figure 2: Catecholates for the immobilization on ZnO NPs.
Figure 3: A) XRD pattern of ZnO NPs obtained by the colloidal suspension of Zn(acac)2. B) TEM image of pure Z...
Figure 4: A) TGA data of catecholates 3, 13 and 14 immobilized on ZnO NPs: pure ZnO NPs treated with MOPS buf...
Figure 5: A) TGA data of catecholates 3 and 14 immobilized on ZnO NPs: pure ZnO NPs treated with MOPS buffer ...
Figure 6: TEM images of ZnO NPs. A) ZnO NPs coated with monomeric PEG-catecholate 14 after washing with water...